WATER REDUCER, SUPERPLASTICIZERS AND RETARDERS

WATER REDUCER


Workability of fresh or plastic concrete requires more water than is needed for hydration. The excess water, beyond the hydration requirements, is detrimental to all desirable properties of hardened concrete. Therefore, water-reducing admixtures have been developed to gain workability and, at the same time, maintain quality.

Water reducers increase the mobility of the cement particles in the plastic mix, allowing workability to be achieved at lower water contents. Water reducers are produced with different levels of effectiveness: conventional, mid-range, and high range. Figure 1. shows concrete without the addition of admixture and with the addition of conventional, mid-range, and high-range water reducers. As shown in the figure, the slump of the concrete increases, indicating an increase in workability. The high-range water reducer is typically called plasticizer or superplasticizer.

SUPERPLASTICIZERS

Superplasticizers (plasticizers), or high-range water reducers, can either greatly increase the flow of the fresh concrete or reduce the amount of water required for a given consistency. For example, adding a superplasticizer to a concrete with a 75-mm (3 in.) slump can increase the slump to 230 mm (9 in.), or the original slump can be maintained by reducing the water content 12% to 30%. Reducing the amount of mixing water reduces the water–cement ratio, which in turn, increases the strength of hardened concrete. In fact, the use of superplasticizers has resulted in a major breakthrough in the concrete industry. Now, high-strength concrete in the order of 70–80 MPa (10,000-12,000 psi) compressive strength or more can be produced when superplasticizers are used. Superplasticizers can be used when:

1. a low water–cement ratio is beneficial (e.g., high-strength concrete, early
    strength gain, and reduced porosity)
2. placing thin sections
3. placing concrete around tightly spaced reinforcing steel
4. placing cement underwater
5. placing concrete by pumping
6. consolidating the concrete is difficult

When superplasticizers are used, the fresh concrete stays workable for a short time, 30–60 minutes, and is followed by rapid loss in workability. Superplasticizers are usually added at the plant to ensure consistency of the concrete. In critical situations, they can be added at the jobsite, but the concrete should be thoroughly mixed following the addition of the admixture. The setting time varies with the type of agents, the amount used, and the interactions with other admixtures used in the concrete.

RETARDERS

Some construction conditions require that the time between mixing and placing or finishing the concrete be increased. In such cases, retarders can be used to delay the initial set of concrete. Retarders are used for several reasons, such as the following:

1. offsetting the effect of hot weather
2. allowing for unusual placement or long haul distances
3. providing time for special finishes (e.g., exposed aggregate)

Retarders can reduce the strength of concrete at early ages (e.g., one to three days). In addition, some retarders entrain air and improve workability. Other retarders increase the time required for the initial set but reduce the time between the initial and final set. The properties of retarders vary with the materials used in the mix and with job conditions. Thus, the use and effect of retarders must be evaluated experimentally during the mix design process.

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